Scientific Measurement I. Quantitative vs. Qualitative A. Quantitative is a measurement. It is expressed in numbers. B. Qualitative is a description. II. Accuracy and Precision A. Accuracy indicates the closeness of the measurement to the actual value. B. Precision indicates the reproducibility of the measurement. III. Significant Digits or Significant Figures (sig figs) Measurements are reported using all digits accurately known plus a last digit that is estimated. Rules A digit is SIGNIFICANT if it is: a. a non-zero. b. a zero between non-zero digits. 205 1001 40.4 c. a zero at the end of a decimal number 11.0 700. 80.0 A digit is NOT SIGNIFICANT if it is: a. a zeros before a non-zero 0.025 b. a zero at the end with no decimal point 300 10 Significant Figures in Calculations 1. Addition and Subtraction Answer gets the same number of digits after the decimal as the original number with the least number of digits after the decimal 1.1 m + 10.557 m ----------- 17.20 g - 0.5263 g ------------ 2. Multiplication and Division Answer gets the same number of total significant digits as the original number with the least number of total significant digits 25 x 3.75 = 93.75 round to 94 8.00/2.00 = Round answers at the end of your calculations. IV. SI Units Used worldwide in the scientific community. Quantity Length Volume Mass Density Temperature base unit m m3 kg g/cm3 K also used L g/ml o C Metric Prefixes kilo deci centi k d c 103 10-1 10-2 milli micro nano pico m n p 10-3 10-6 10-9 10-12 V. Volume the amount of space matter takes up derived from length v=lxwxh liquid volume measured in a graduated cylinder m3 L(dm3) mL(cm3, cc) VI. Mass amount of matter in an object measured on a balance grams (g) VII. Density the amount of matter in a given space density will change with temperature because volume changes with temp. density = mass divided by volume m d= v units: g/ml or g/cm3 VIII. Specific Gravity compares density of a substance to density of water has no units density spec. grav. = density of water IX. Temperature measure of hotness or lack of heat average kinetic energy A. Heat Transfer from high heat to low heat B. Temp. affects volume in general: T goes up, V goes up (material expands) T goes down, V goes down (material contracts) H2O is an exception, solid is less dense than liquid C. Units: Celsius and Kelvin 0 K is absolute zero, temp. where all molecular motion theoretically stops 0 K = -273oC o K = oC + 273 C = K – 273 X. Error in Measurements Human error – biggest source misreading the instrument calculation errors carelessness Instruments Problem Solving Techniques 1. Identify the unknown. What is the problem asking? 2. Identify and list what is known or given. 3. Plan a solution. Write down the equations you will need. Draw a picture if it will help. Write down any constants or conversion factors. 4. Do the calculation. Plug and chug. 5. Finish up. Are your units correct? Does the answer have proper significant digits? Put a box around your answer. Check your work! Conversions Conversion Factors ratio of equivalent measurements fractions where the numerator and denominator represent the same quantity, units are different Examples: 1 dollar 100 cents or 100 cents 1 dollar 1m 1000mm or 1000mm 1m used to convert from one unit to another can be used to solve problems (called dimensional analysis or factor label method) can be used in multi-step problems Examples: 1. How many grams are in 15kg? 1000g 15kg x 1kg = 15000g (kg cancel) 2. How many second are in 1 day? 24hrs 60 min 60sec 1day x 1day x 1hr x 1min = 86400 sec
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